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MU's Carbon Recycling Lab at work on water-recycling toilet

Tuesday, July 9, 2013 | 6:00 a.m. CDT; updated 8:54 a.m. CDT, Wednesday, July 10, 2013
MU and Duke University have partnered to create a toilet that uses less water as part of the Bill and Melinda Gates Foundation's Reinvent the Toilet Challenge.

COLUMBIA — Miso soybean paste, cellulose, yeast, psyllium husk, oleic acid, sodium chloride, potassium chloride and calcium chloride.

That's a recipe for fake poop.

Engineers at MU’s Carbon Recycling Center are getting pretty good at processing this hummus-colored sludge with their water-recycling toilet. Their effort is part of the Reinvent the Toilet Challenge, sponsored by the Bill and Melinda Gates Foundation. The MU lab is working with engineers at Duke University to develop a new toilet technology for water-scarce parts of the world.

“The problem is, everybody creates poop,” said Nikolas Wilkinson, a recent master’s degree graduate working in the lab over the summer. “And it’s obviously biologically hazardous, so you have to do something with it.”

Toilets in the developed world use between 1 1/2 and three gallons of water with every flush. People in developing countries who are caught in the stranglehold of water scarcity can’t afford to waste so much precious drinking water. Solving this problem means rethinking how water is used to process solid waste. 

The MU lab's experimental toilet uses water like an ordinary toilet, but because the water it uses is superheated and super-pressurized, its toilet can do what ordinary toilets can’t — dissolve waste and then fully consume it in an intense, heat-producing oxidation reaction.

“The big idea is that when it’s done, you’re going to be able be able to recover all the water,” said Brook Remington, an undergraduate student who works in the lab. “You’re going to end up with clean, sterile water at the end.”

The water used in the reaction is heated to about 1,100 degrees Fahrenheit and 250 times the normal atmospheric pressure, Wilkinson said. Because of the heat, it should be a gas. Because of the pressure, it can't be. When a liquid undergoes such an identity crisis, it becomes "supercritical." 

Supercritical water has unique properties. The water spreads out to fill as much space as possible, like a gas, but it also can dissolve solids as it would in liquid form.

Dissolving the waste makes for a more efficient reaction because it increases the surface area of the fuel.

“If you had a giant wood log, it would only burn at the surface,” Wilkinson said. “Since we can dissolve it in there, we have a lot more surface area per mass, and so we can get really high reaction rates.”

The toilet works like this:

Three thin pipes lead to a small metal cube. One tube carries supercritical water and another provides oxygen. The third tube delivers solid waste at a minimum of 4.5 milliliters per minute. When the three inputs meet inside the metal cube, the reaction begins.

Wilkinson and Remington speak of the solid waste “burning,” but they’re quick to point out that it doesn’t burn with an open flame, the way a log would. Despite their understanding of the chemistry at work, they have a hard time forming a mental image of exactly what goes on inside the metal cube.

“It’s very difficult to picture,” Remington said.

“The way I think of it, just as a simplistic model in my head, is if you had three hoses and you just shoot them at the same point and they get kind of chaotic,” Wilkinson said. “Except in this case it’s all going out one tube at the end.”

The mixture that forms in the cube flows into a coil of thin pipe, where the water cools as the waste is consumed, leaving only clean water, carbon dioxide and a few solids.

The beauty of this toilet is its potential for promoting reuse of materials and energy, Wilkinson said. Water fed into the reaction emerges clean. The heat generated can be used to preheat water for the next round. The solids byproducts, such as nitrogen and phosphorus, could be used for fertilizer.

Some major challenges will have to be resolved before the toilets can be put to widespread use.

Supercritical water is highly corrosive, Wilkinson said, and the engineers often have to replace metal pipes and joints that come into frequent contact with the water. The waste tube also tends to clog.

Finally, the engineers have to fine-tune the heat, pressure and oxygen concentration to create the most effective reaction. After they finish their work on the project, they will hand it off to Duke University.

Doug Hendry, who earned his Ph.D. at MU in 2012, moved to Durham, N.C., last week to continue the project at Duke. Hendry said Duke's version of the toilet will be four to six times larger and will fit in a 20-foot shipping container so it can be sent abroad. 

Construction on the Duke version will begin in September, Hendry said. He expects it will be operational by March 2014. 

The MU-Duke partnership came about after Duke received a $1.2 million grant from the Gates Foundation. Duke had originally intended to work with a private company, MU biological and chemical engineering professor Bill Jacoby said. Then the deal fell through, and Duke professor Marc Deshusses turned to MU after reading some of the publications on solid waste treatment that Jacoby and his students produced.

For about five years, the engineers in MU’s Carbon Recycling Center have been studying the use of supercritical water oxidation for solid waste disposal. Personnel from the MU and Duke labs began meeting in January, Jacoby said. MU received $200,00 of Duke's grant money and began work on the project in April.

Jacoby emphasizes the crucial importance of biomass, a catch-all name for living or recently living tissues. Nearly every type of fuel is, or once was, biomass. Exploring new ways to use biomass is his lab’s mission.

“Biomass is our carbon resource,” Jacoby said. “It’s our only carbon resource.”

Supervising editor is Scott Swafford.


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Comments

Ellis Smith July 9, 2013 | 11:32 a.m.

Interesting.

Another technology, in use for years now, is the "incinerating toilet." Toilets are commercially available, and have these advantages:

1- Uses NO water OR chemicals at all! (Does require a compressed fuel source, such as propane.)

2- The incinerated ash is fine, sterile and can be trashed or buried.

3- Systems are portable and easy to install.

4- Excellent for remote areas, especially those with below freezing ambient temperatures.

5- Relatively odorless. (Key word is "relatively.")

These units have seen many installations in Canada (see point 4, above), either for summer-use cabins or year around in areas where permafrost is present.

One of my former corporate employers had a Canadian subsidiary that made refractory ceramic chambers used in combustion of the "waste." Refractory ceramic fibers (RCFs) were slurried with water and an inorganic binder, the slurry was vacuum-formed into the reqired shapes, and the formed shapes were cured in an oven. Definitely not rocket science!

The RCF combustion chambers had to be periodically replaced, so this was excellent repeat business. It was also the butt of many in-house jokes, usually dealing with the consequences SHOULD SOMEONE BE SITTING ON THE TOILET WHEN AN INCINERATION CYCLE BEGAN. (The toilets were designed so that couldn't happen.)

EPA has a fact sheet (EPA 832-F-99-072, September 1999) available: "Water Efficiency/Technology Fact Sheet/Incinerating Toilets." Try finding this using a word search engine: incinerating toilets.

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